This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.
Beilstein J. Org. Chem. 2020, 16, 2671–2678, doi:10.3762/bjoc.16.217
Graphical Abstract
Figure 1: Anti-HIV compound containing a trifluoromethylpropargylamine moiety.
Scheme 1: Literature-known methods (a and b) and the here reported (c) approach for the synthesis of α-triflu...
Scheme 2: Substrate scope study. Reaction conditions: arylethyne 2 (0.39 mmol), imine 1 (0.3 mmol), LiHMDS (0...
Figure 2: ORTEP diagram showing of the minor product of 3a.
Figure 3: Mode of nucleophilic attacks A and B.
Scheme 3: Large-scale application of the reaction.
Scheme 4: Removal of the chiral auxiliary.
Beilstein J. Org. Chem. 2014, 10, 442–448, doi:10.3762/bjoc.10.41
Figure 1: A family of chiral and achiral equivalents of nucleophilic glycine.
Scheme 1: Synthesis of chiral ligands 4a–f.
Scheme 2: Preparation of diastereomeric Ni(II) complexes 5a–f and 6a–f.
Figure 2: Crystallographic structure of (SCRN)-5b.
Figure 3: Crystallographic structure of (SCRN)-5b showing an exposure of the methyl moiety of α-phenylethylam...